Hi @CWT :
So lets go through each one:
1) In this scenario you would need to seize quorum and mount the databases in Site 2. If you have DAC Mode enabled, you can use the built-in PS commands to do that and essentially its a datacenter switchover. If DAC mode is not enabled, the cluster Commands are needed:
https://learn.microsoft.com/en-us/exchange/high-availability/manage-ha/datacenter-switchovers?view=exchserver-2019
Easily is a loaded word :) Enable DAC mode if you haven't already and you can use the Exchange PS commands to do this in the event it ever happens.
Here is the thing, you have done the right thing by having 2 peer datacenters and a FSW in a third site, but its important you know what to do in the hopefully rare time you lose the connection to two sites at the same time. If that did happen, it would probably be a WAN loss more than anything - and even if you did lose both sites, you would have to then determine how long it may be down and whether its worth seizing quorum in the standing data center.
2) The alternate witness is a misnomer actually. Its not needed and its really nothing more than a configuration setting. You are essentially telling the DAG that if I need to do a datacenter switchover ( see 1 above), then use this as the FSW. Its not a backup nor can it automatically kick in when needed in a 4th site. You actually would never use the alternate witness except in a datacenter switchover. So, to answer your question, it can't be used to provide any sort of high availability.