The personal Accounts won't convert into a business account. There will be always a private and a business account then. It doesn't effect the user at all in my experiance as for login into PC's always the business account is taken when the devices are registerd in the related azure active directory domain. If you login to the webportal of office user has two accounts then as a choice and needs to take the business account thats normal behavior.
Anyways you will gonna have more problems with the windows 10 home os versions.
Windows 10 Home edition cannot be joined to a domain.
Beside that Windows AutoPilot supports the following Windows 10 operating system editions:
Windows 10 Pro
Windows 10 Pro Education
Windows 10 Pro for Workstations
Windows 10 Enterprise
Windows 10 Education
-Windows 10 Enterprise 2019 LTSC
If you want to domain join your computer, you'll need to upgrade to Windows 10 Professional.
Upgrade Windows 10 Home to Windows 10 Pro
https://support.microsoft.com/en-us/help/12384/windows-10-upgrading-home-to-pro
As a possible migrationpath i would setup a tenant with intune and everything and all user accounts and then update the machine step by step reset them and let them do an autopilot roleout into the business tenannt.