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For sync AD account, you need to modify from the local AD (ADUC). Many of attributes cannot modified from the Exchange online side.
For emails address, you need to modify the "proxyAddresses" value from the ADUC. Such as "smtp: User@keyman .com". Then wait the sync of AAD Connect.
If there doesn't exist Exchange on-premises server, I would suggest you run prepare command with Exchange server ISO on your local AD. Otherwise, you cannot see the mail related attributes and modify from the local AD.
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