I would recommend you to deploy a Run Registry Key instead. You can still deploy that with Group Policy:
If you want to deploy this on a Computer (so that it applies to everyone logging in on the computer), then, in your GPO, go to Computer Configuration -> Preferences (not "Policies") -> Windows Settings -> Registry -> New Registry Item, and create a new REG_SZ value under the path shown in the documentation (HKEY_LOCAL_MACHINE\Software\Microsoft\Windows\CurrentVersion\Run), give it a meaningful Value name, and set the Value data to be the path of the executable on the computer.
If you want to deploy this setting on a per-user basis, then use the same method but on User Configuration instead of Computer Configuration (and HKEY_CURRENT_USER\Software\Microsoft\Windows\CurrentVersion\Run instead of HKLM).
Hope this resolves your Query !!
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