Hi,
I'd be happy to help you out with your question. Sorry for the inconvenience caused.
There are a few possible workarounds:
You could try using a different method to load the WinUI3 classes. There are a few different ways to do this, and you can find more information in the WinUI3 documentation.
You could try publishing your app outside of the Microsoft Store. This would allow you to call the Bootstrap Initialize function, but it would also mean that your app would not be available to users who install apps from the Microsoft Store.
For more Information, please refer to following resource :-
Tutorial--Use the bootstrapper API in an app packaged with external location or unpackaged that uses the Windows App SDK - https://learn.microsoft.com/windows/apps/windows-app-sdk/tutorial-unpackaged-deployment
If you have any other questions or need assistance with anything, please don't hesitate to let me know. I'm here to help.
If the reply was helpful, please don’t forget to upvote or accept as answer, thank you.