@Siripurapu Sanjeev Kumar, Thanks for posting in Q&A.
According to your description, I know that you want to know how to fix error while uploading win32 app via Intune.
Could you please help me confirm some information? Is this error code appeared when you click to upload? If yes, please check whether your win32 app package exceeds 8GB.
If no, this error message may be related to the deployment of win32 app.
Please check the IME log error message on the targeted device and share the screenshot with us, location: C:\ProgramData\Microsoft\IntuneManagementExtension\Logs\IntuneManagementExtension.log.
Here is a link deep dive to IME log:
Intune Management Extension Level 3 Troubleshooting Guide (anoopcnair.com)
Moreover, you can check whether Install behavior is configured to System.
Please try above information, if there is any update, feel free to contact me.
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