@Deepu Madhusoodanan Thanks for reaching out to Microsoft Q&A, apologize for any inconvenience caused on this.
Usually, DNS changes take up to 15-30 mins to take place, which means after adding the DKIM/DKIM2 value, it will take extra 30 mins to reflect the Verified status. Can you check and let us know if you are still facing the issue?
And also, it is recommended to set TTL of SPF/DKIM records as 1hour/3600 seconds.
If the issue still remains, could you please help us with the ACS resource name, custom domain name, Last 4 digits of your subscription id to check and assist you further on this.
Solution : Upon investigating deeper customer found that he made a typo while configuring the DKIM2 records.