From what you have described you'll be creating a new domain and the desktop machines will need to be joined to the new domain. I'd make sure you know the local administrator account passwords on the desktops as first step.
If you wanted to preserve the existing domain then I'd stand up a new interim domain controller as first step. (even a desktop will do for this purpose)
The two prerequisites to introducing the first 2019 domain controller are that domain functional level needs to be 2008 or higher and older sysvol FRS replication needs to have been migrated to DFSR
https://techcommunity.microsoft.com/t5/Storage-at-Microsoft/Streamlined-Migration-of-FRS-to-DFSR-SYSVOL/ba-p/425405
I'd use dcdiag / repadmin tools to verify health correcting all errors found
before starting any
operations. Then stand up the new 2019, patch it fully, license it, join existing domain, add active directory domain services, promote it also making it a GC (recommended), transfer FSMO roles over (optional), transfer pdc emulator role (optional), use dcdiag / repadmin tools to again verify health, when all is good you can decommission / demote old one.
--please don't forget to Accept as answer if the reply is helpful--