A cloud-based identity and access management service for securing user authentication and resource access
Hi @Lucas W
Thank you for posting your query on Microsoft Q&A.
I understand that you are trying to prioritize Cisco Duo over the Microsoft Authenticator app whenever it comes to MFA.
Try to create a conditional access policy in which select the targeted users for whom you want to prioritize Cisco Duo over the Microsoft Authenticator app.
Under grant access select Require Multifactor Authentication>Require DuoMFA.
Then when the user login he is prompted for Cisco Duo MFA.
Hope this helps. Do let us know if you have any further queries.
If this answers your query, do click `Accept Answer` and `Yes`.
Thanks,
B. Siri Chandana.