Hello,
The Remote Desktop Protocol will usually try to restore an existing session instead of creating a new one, especially when the username and server address are the same. This is to save resources and provide a consistent user experience.
In order to open multiple sessions as the same user on the same server, please check the Group Policy settings on the server again. Navigate to Computer Configuration > Administrative Templates > Windows Components > Remote Desktop Services > Remote Desktop Session Host > Connections. Then, disable the policy in the figure below. After confirmation, use the “gpupdate /force” command to force a refresh.
Note: Serious problems might occur if you modify the Group Policy incorrectly. Therefore, make sure that you follow these steps carefully. For further protection, back up the Group Policy before you modify it. For more information about how to back up and restore the group policy, refer to Backup and restore Group Policy in Windows | Microsoft Learn
If you have any confusion about this issue in the future, please let us know.
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Best regards,
Jacen Wang