@Ashutosh Thakur , Firstly, apologies for any inconvenience.
Just to clarify, did you provision this WebApp only just before ~30 hrs? /Is this a new WebApp (just recently deployed)?
What App Service Plan are you using? In which region have you provisioned the WebApp? Were there any changes just before the issue started?
This (503 -service unavailable) problem is often caused by application level issues, such as:
- requests taking a long time
- application using high memory/CPU
- application crashing due to an exception.
To start with - In Azure Portal > On the App Service App, in the left navigation, click on Diagnose and solve problems – Checkout the tile for “Diagnostic Tools” > “Availability and Performance” & "Best Practices", to fetch more details on the error.