@Priyaranjan Sathyavrathan Thanks for reaching out.
Security default does not prompt for users every time they log in. They will be prompted primarily when they are coming from a new Device or application or performing critical roles and tasks only.
Security defaults make the following admin perform MFA everytime they login :
Global administrator
SharePoint administrator
Exchange administrator
Conditional Access administrator
Security administrator
Helpdesk administrator
Billing administrator
User administrator
Authentication administrator
So the behavior you are seeing is expected for most of the scenarios.
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