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On my Windows 7 professional system. The highlighted icon in the attached image appears on every reboot. Clicking on it open Windows explorer. As far as I understand it looks like a 'generic volume' icon similar to one in device manager.
However, I don't understand why it's opening My Computer
It looks like the icon for a (network or not) mapped drive
which is disconnected
Thanks the the response Castorix31.
I'm still wondering why does it open windows explorer on clicking it.
This is normal when you click on an icon from File Explorer
For example, on my PC, I have at boot a similar icon because I have waiting files to be burned on CD, and If I click on it, it also opens Explorer on the CD drive