I have the same issue: A file saved as a .docx that gives the same error when opening in Word 2013. I changed the extension to .zip. It is not a zip file. I changed the extension to .doc and it fails to open with message: Microsoft Word cannot open
this file because it is an unsupported file type. Then I changed the extension to .txt and opened it in notepad. It appears very much to be a .doc file. The last line contains the following: <ds:datastoreItem ds:itemID="{A87D756C-51E1-4CB4-ADBE-8F921D4509B4}"
xmlns:ds="http://schemas.openxmlformats.org/officeDocument/2006/customXml"><ds:schemaRefs><ds:schemaRef ds:uri="http://schemas.openxmlformats.org/officeDocument/2006/bibliography"/></ds:schemaRefs></ds:datastoreItem>
þÿ ÿÿÿÿ›Luôõd@KŠôg—2¬ Microsoft Word Document MSWordDoc Word.Document.12 ô9²q (BTW, Opening another working .doc file I have shows something similar in the last line: <ds:datastoreItem ds:itemID="{D6CCB430-7B4E-4E48-8A3A-2FC8E3D09CF8}"
xmlns:ds="http://schemas.openxmlformats.org/officeDocument/2006/customXml"><ds:schemaRefs><ds:schemaRef ds:uri="http://schemas.openxmlformats.org/officeDocument/2006/bibliography"/></ds:schemaRefs></ds:datastoreItem>
þÿ ÿÿÿÿ À F Microsoft Word 97-2003 Document MSWordDoc Word.Document.8) The file started from a .dot file, and at some point was saved as a .docx by a user. We could go through all our .dot templates and upgrade them to a newer
version, but there's a lot of work involved, so would prefer (in the short term) to avoid what appears to be a weird mix of versions happening. Any ideas?
EDIT: Found that the file was saved as a document and not a zip file. (i.e. As detailed above, changing the extension to .zip didn't reveal a zipped folder structure and the text of the file (when opened in Notepad) contained Word.Document in the last line.
But it wasn't just any ordinary document. It was an 'auto-save' recovery document. To restore it, I changed the extension to .asd, placed the file in Word's auto-recovery location and then opened Word, File->Open, navigated to the auto-recovery folder (which
you can find in Options), showed all files (*.*) and simply opened it. Not sure how it ended up in that format, so not sure how common this would be.