A family of Microsoft spreadsheet software with tools for analyzing, charting, and communicating data.
I solved the problem.
First, I uninstalled Office 12.
I then found I could not open Office files at all by double clicking on them in Explorer. The error said I needed to have the Program installed. The defaults for Excel were still version 16 and the files would open if I opened Excel first.
I then went into settings for Office 16 and selected the Modify/repair options.
This seems to have fixed everything and my Excel (and other) files open properly from Explorer.
Thanks to all of you for your comments.