Though we dont find that job when logged in as sa user
As SysAdmin "sa" you can see everything in SQL Server, no need to logon with a different account.
That the service account as user issues the backup do not necessarily mean, it's done by a SQL Server-Agent job, it can also be done with Windows Scheduler, where the service account is assigned to the schedule.
See Schedule and automate backups of SQL Server databases in SQL Server Express