Hello. Outlook for Mac (both New and Legacy) does not let you change the background color or shade used to highlight the selected message in the message list. That color is predetermined by the app’s theme and macOS system settings, and is not configurable within Outlook itself.
You can:
- Go to System Preferences → General → Highlight color and pick a more visible color.
- Enable Accessibility → Display → Increase Contrast to make UI elements, including selection rows, more distinct.
These changes apply globally on macOS, not just Outlook.