Using New Outlook on Windows for personal email, calendar, and contact management
Well, that wasn't much help either. We are a home account, and it would appear Support chat is not available for us.
I tried a suggestion given in response to another Microsoft user - where it was clear that MANY people have this same problem, and typically the suggested solutions do NOT work or are simply not available when you enter Accounts.
Solution I tried was to type Windows + R, type 'Control Panel' into the dialog box and then go down the thread to Credential Manager. There I found the offending account from work, and removed it.
Turned the computer off and on again, twice. Each time, when I went to log in to Copilot or Outlook, guess which address showed up first? Yep, my work account from 2021.
I have no idea what "Classic Outlook" is, and don't wish to try it. In fact, why should we have to go to a redundant version of Outlook to find the solution to a current version problem anyway?
Given that this issue has annoyed and frustrated several users, it would seem to be one that needs fixing at the company, not by wasting the hours of those who pay to use its products!