Thank you for reaching out to the Microsoft Q&A Forum and I am sorry for the inconvenience this account conflict is causing. To help us scope the issue efficiently and, importantly, to protect your privacy, please reply via private message with brief answers to the questions below:
- What exactly is the Microsoft personal email address that is affected?
- Has your company fully completed the migration from Google Workspace to Microsoft 365, or is it still in progress?
- Can you sign in to Outlook on the web with your Microsoft work account?
- When you add the work account in Outlook for iOS, what exactly happens. Please share the brief error text or the observed behavior?
- When adding the account, did you choose the Work or School option for Microsoft 365, or did you choose Google or Other.
Once I receive your responses, I will quickly provide the most appropriate next steps to ensure you can access your Microsoft work mailbox on your iPhone without confusion between accounts.
Thank you for your patience and your understanding. I look forward to continuing the conversation.