Hello,
Is this your personal account outlook.com?
There's no such storage plan that's premium 6TB. Could you possibly mean you purchased the Microsoft 365 Premium? If so, that plan allows you to share with another 5 users, and each user can have 1TB of OneDrive storage, that storage cannot be pooled for one user.
In addition, when you upgrade to a Microsoft 365 plan, it only increases your mailbox size to 100GB, not 1TB. The 1TB is for OneDrive. You can refer the information here: https://support.microsoft.com/en-us/office/storage-limits-in-outlook-com-7ac99134-69e5-4619-ac0b-2d313bba5e9e
It can also take 48 hours to reflect the change. So if you made the purchase during the last 48 hours, please wait.