On your laptop, you have one processor, you do not have 16 processors, your processor like all modern processor has multiple cores and threads, but only one processor.
WIndows is a multi-threaded operating system and so are most games and apps and large tasks are split up between the many cores/threads on the processor to make your system more efficient.
I presume the setting you are trying to change is in the MSConfig utility on the Boot - Advanced tab, is that correct?
If so, do not change that setting, that may cause WIndows not to boot up, and you would either need to run a couple of commands in the recovery environment to get Windows working again or may even need to re-install Windows.