The administration of a hybrid deployment that connects on-premises Exchange Server with Exchange Online, enabling seamless integration and centralized control.
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In a Hybrid Exchange environment with Azure AD Connect (DirSync), the security group (or mail-enabled security group) is typically “on-premises mastered.” That means Exchange Online / the Exchange admin center in Microsoft 365 won’t allow you to directly change certain attributes for that synced group, and you’ll see errors when trying to add/update them in the cloud UI.
Microsoft’s guidance is that synced groups must be managed using on-premises Exchange tools, then the changes will synchronize to Microsoft 365, so you can follow the instructions below:
1/ Determine whether the group is synchronized (DirSync) or cloud-only
If the group is synchronized from on-premises, you must make alias/email address changes on-premises and let AAD Connect sync them to Exchange Online.
2/ For DirSync (on-premises mastered) groups: update on-premises, then sync
Manage the group using on-premises Exchange tools (Exchange Admin Center / Exchange Management Shell). After you update the alias/email addresses on-premises, allow directory synchronization to replicate the change to Microsoft 365 (or trigger a sync if you need it reflected sooner).
3/ Validate mail delivery behavior for the group
Confirm the object is a mail-enabled security group and review its mail settings in EAC (recipients/groups). Mail-enabled security groups are managed through EAC, and Microsoft documents the supported management paths and what can be configured (including email address properties).
Hope my answer will help you.
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