Windows has no control over the actions associated to the function keys on your keyboard, that is always controlled by the PC manufacturer.
1
Press Fn + Esc on your keyboard to test if that toggles the Function Lock on your keyboard off.
2
If not, boot your system into BIOS.
Look for a setting in there to toggle between Function Keys and Media/Action Keys and apply that.
3
If that does not resolve the problem, click your Start Button, then just type msinfo and press Enter, please provide a screenshot of the resulting System Information window.