Hello, are you using a Microsoft email account like Outlook.com, Microsoft 365, or a third party email provider?
In Outlook 2013, remove and re add the account using the Auto Account Setup instead of manual settings. Go to File, Account Settings, then remove the affected account. Restart Outlook, then add the account again using your full email and password. This lets Outlook apply modern authentication and correct SMTP settings automatically, which often resolves the 530 error when manual settings fail.