Hi,
Are you signed in to the same account in both your subscription page and Outlook.com?
Go to Outlook.com, select your profile picture, then choose My Microsoft account and confirm your Microsoft 365 subscription is active under Services and subscriptions using the same email. Next, sign out of Outlook.com, clear your browser cache, then sign back in. After that, go to Settings > General > Storage and click Refresh or open OneDrive and check storage there, then return to Outlook.com.
If it still shows 5 GB, remove and re-add the account in any connected apps like Outlook desktop or mobile, then wait a few minutes and test again. This will force your account to sync the updated storage quota and restore email flow.