Hello SgtGracious,
Thanks for getting back to me.
I also think that this is a thermal issue, PC temperature can go up to 95-100 Celsius when dealing with heavy workload but go up to 105 is way past the safe threshold. That is also related to event 125, which means the hardware thermal sensor zone is loading threshold for it and might consider force shutdown computer to protect the device.
Usually, this often link to super heavy load to the computer or overclocking. However, if it happens out of nowhere, it's most likely that some hardware might not functioning well (OS and software issue will raise the temperature gradually instead of a large spike). Changing the thermal paste is a great idea, the cooling has already failed, so you should change it even though it might not be the main cause. Also, you should check the other hardware part as well to see if everything is okay. Thank you for your understanding.