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Hey there, humaira bibi
Please can you make sure you are signing into the Microsoft MVP portal (https://mvp.microsoft.com/account) using your personal Microsoft account. It could be that you are trying to sign into the portal with your organisational account.
Once you have done this, please can you try and link your account to your Azure Student Subscription. If you are continuing to have problems with this, please reach out to the Microsoft Student Ambassador team by emailing them at sa-help@microsoft.com
They will be able to help further with this.
I also previously got "AADSTS50177: User account does not exist in tenant 'Microsoft'" when trying via a different flow
This is expected, when you haven't been added to the Microsoft tenant as a guest. When signing in, the sign-in process checks whether the account is a member of the tenant either as a guest or member. I would stick to the flow on the official pages.
Hope this helps & good look!
Nathan