Hello Eladio Vega Bestard,
Welcome to the Microsoft Q&A and thank you for posting your questions here.
I understand that your Flexible Server stuck in "Starting" for 2 days - ServerBusyWithOtherOperation, platform-initiated start also hangs.
Your Azure Database for PostgreSQL Flexible Server backend operation that did not complete cleanly after the scheduled start operation returned 202 Accepted and later timed out. Since the server is still in Starting and new operations are rejected as ServerBusyWithOtherOperation, do not keep retrying Start, Stop, Restart, Scale, or configuration changes.
Proceed with Point-in-Time Restore to a new Flexible Server, validate the restored server, and cut over the application to the new endpoint as a recovery. PITR creates a new server from the source server backups and does not overwrite the original server. Use Latest restore point (Now) unless you have a specific known-good restore timestamp. - https://learn.microsoft.com/en-us/azure/postgresql/backup-restore/how-to-restore-latest-restore-point, and https://learn.microsoft.com/en-us/azure/postgresql/backup-restore/concepts-backup-restore give more insights.
After the new server is created, restore service by updating the application connection string, validating firewall rules, private endpoint or VNet access, DNS, users, roles, permissions, server parameters, extensions, alerts, and application writes.
For the original server, first check Resource Health for the affected server. If it shows Unavailable, Degraded, Unknown, planned event, or unplanned platform event, open the support request from Resource Health. The next required action is Microsoft backend/Product Group engagement via your Portal or contact priority customer support (PCS). There is no supported customer-side command to force-cancel or unlock a stuck Flexible Server control-plane operation.
Also, there is no confirmed public evidence from the details provided that Spain Central had a broad regional outage. However, use Resource Health and Service Health to validate whether this was a platform, capacity, maintenance, or resource-specific backend issue. - https://learn.microsoft.com/en-us/azure/service-health/resource-health-overview. Use the associated resource links for more reading and steps
I hope this is helpful. Please! Do not hesitate to let me know if you have any other questions, steps or clarifications.
Please do not close the thread by upvoting and accepting the answer if any part of it is helpful.