Hi,
- What is the make and model of the computer?
nvspcap64.dll and shadow play are files related to NVidia but to confirm this let's place the computer in Clean boot state to find out the exact software that is causing this issue on Startup.
http://support.microsoft.com/kb/929135
Note: Once done troubleshooting, place the computer back to normal mode by following the steps mentioned in "How to reset the computer to start as usual after clean boot troubleshooting "
If the issue is confirmed with NVidia, then I would suggest you to uninstall NVidia software/drivers installed on the computer and reinstall them from the computer manufacturer website and check.
- Go to Device Manager with the help of Search Charms.
- Browse Display adapters, right click on NVidia and click on Uninstall.
- Restart the computer and then Windows will automatically try to install the drivers. If it fails, then check for Windows update and install the NVidia drivers offered.
Let us know if this helps.