Hi ChaitanyaKiran-2787,
Yes. But please note that A table can contain only one PRIMARY KEY constraint. Any relationships to the existing primary key must be deleted before the new primary key can be created.
Please check https://learn.microsoft.com/en-us/sql/relational-databases/tables/create-primary-keys?view=sql-server-ver15 for more details.
Best Regards,
Amelia
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