Hi,
I think you're just doing this in the wrong place. Change the Network Adaptor rather than the whole system.
In the Network Status page, click Change Adaptor Options.
An explorer window should open it will will usually show all of your network adaptors, for me it has the Bluetooth, Ethernet and Wifi adaptors.
I'm using Ethernet so I double click on that and then select Properties.
In the list of protocols, select Internet Protocol Version 4 (TCP/IPv4) and Properties.
Now you can update the values you want to.
Repeat for IPv6 and/or any other adaptors you want.