It should just do it by default. Example of a test I just ran: enabled network sharing on a Windows 10 PC and shared a User folder named "test". Transferring from a Windows 11 PC to the Windows 10 PC transferred at 1000Mbps or approx 100MB/s of a 2GB file in the correct amount of time while using File Explorer.
Both computers are connected via integrated 1GigE ethernet hardware with cat 5e cables, switch, and router. Nothing else was done. No networking driver configuration or Windows networking configuration on Windows. The Windows 11 OS was reinstalled clean to drive swap in the best way possible a few months ago and the Windows 10 PC was installed clean earlier this year I believe it was. They both use Windows supplied networking drivers.
That tells me that something about your computer or network isn't working right. But, I've no idea what since by default Windows does more than "Windows explorer transfer speed: 5-10MB/s".
Since your internet speed is higher then it suggests a networking hardware driver issue in relation to SMB as the driver can affect SMB (the router can also, etc) or maybe something off with that Windows installation with its SMB installation, etc. Maybe the driver for your networking hardware isn't fully compatible with Windows default settings. Just not sure.
Wish I could give you a better answer. Though, I think this should help narrow it down for you. At least I hope so anyway :)
Additional. The following link might be worth looking into if you haven't already https://learn.microsoft.com/en-us/windows-server/storage/file-server/troubleshoot/troubleshooting-smb
Of course, different manufacturer networking hardware or router, etc should technically also work or otherwise there's something you do with Windows that causes it I would expect.