Hi Özkan TOPAL,
Since these three mailboxes were shared mailboxes, when you assigned the Exchange online license to them, they can login on Outlook on the web, Outlook client, and it is an excepted behavior (since these mailboxes have license). Meanwhile, you also mentioned the normal user mailboxes can be used SMTP relay, and the shared mailboxes assigned licenses couldn’t use SMTP relay. That is because these mailboxes were shared mailbox, even you assigned the license and set password for these shared mailboxes, you still can’t use these mailboxes as SMTP relay. And we strongly recommend you use the normal user mailbox to use SMTP relay.
Thanks for your understanding.
Regards,
Richard