Converting the FileSystemObject's DriveLetter Property

Definition: Returns the drive letter of the specified drive.

DriveLetter

See Drive. In PowerShell you use the same commands whether you’re returning a drive letter from a file, folder, or drive.

PS C:\scripts> Split-Path "C:\scripts " -qualifier
C:

Or, with the folder reference:

(Get-Item c:\scripts).fullname | Split-Path -qualifier

See conversions of other FileSystemObject methods and properties.
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