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I have the same issue. My Azure for Students tenant is blocked due to inactivity (originally activated in 2023).
When I access the Azure Portal, I can see two directories under my account, with two default directories linked to different onmicrosoft.com domains. I cannot switch to the second directory (the one linked to the old subscription) as it returns an authentication error. I believe this blocked/orphaned tenant is preventing me from reactivating Azure for Students , verification completes successfully but signup fails with an unexpected error.
I would like to request reactivation via private message.