A family of Microsoft word processing software products for creating web, email, and print documents.
Your description indicates that a virtual PDF printer is set as the default for printing in Windows. You can change that in Windows Settings. See https://support.microsoft.com/en-us/windows/set-a-default-printer-in-windows-e10cf8b8-e596-b102-bf84-c41022b5036f. Restart Word and then try printing again.