This can usually be easily and safely done using the Disk Management utility in Windows.
1
Right click your Start button and select 'Disk Management' on the resulting menu.
2
In the bottom pane of Disk Management, right click the C drive partition and select Shrink.
Wait for that process to query the drive on how much that partition can be shrunk by.
On the resulting dialog, you will see the amount the C drive partition can be shrunk by, the calculation used is 1000 = 1GB, so for example, 50,000 is 50Gb and 100,000 is 100GB
Set the amount you want for the new data partition and click the Shrink button
Then, wait for that operation to complete, do not interrupt that process.
3
That will result in an Unallocated Space on your drive, right click that and select 'New - Simple Volume', accept the defaults and then wait for that process to complete.