Hello Terry Seagert,
what you are experiencing is a common synchronization failure where the theme cache becomes corrupted or locked, causing the boot initialization sequence to fail back to the default Microsoft theme rather than loading your custom local path.
To resolve this and rebuild the environment correctly, you must clear the corrupted cache elements directly. Navigate through File Explorer to the directory %USERPROFILE%\AppData\Roaming\Microsoft\Windows\Themes and delete the TranscodedWallpaper file entirely. In that same directory, double-click the slideshow.ini file to open it in Notepad, delete all internal text to leave it completely blank, save it, and then change the file properties to Read-only. This procedure breaks the loop of the corrupted cache and forces the operating system to establish a fresh configuration mapped to your specific Background Photos folder. Additionally, you must select "Span" in the Personalization interface so the horizontal resolution stretches precisely across both 1920x1080 display panels. Finally, navigate to Settings, Accounts, Windows backup, and disable the Remember my preferences toggle for Personalization to prevent your Microsoft Account from continually pulling a default synced theme from the cloud and overwriting your local configuration during startup.
Hope this answer brought you some useful information. If it has, please consider accepting the answer so that other people sharing the same issue would benefit too. Thank you :)
VP