Hi,
Windows Hello with two-factor authenticaiton (2FA) works with Remote Desktop. Users with Windows Hello for Business certificate trust can use their credential to authenticate to remote desktop sessions over RDP. When authenticating to the session, biometric gestures can be used if they are enrolled. For more information and configuration steps see Remote Desktop.
Windows Hello does not support Windows 7 clients, so your Windows 10 clients should work fine, as long as they are running build 1703 or later.
More information here:
https://learn.microsoft.com/en-us/windows/security/identity-protection/hello-for-business/hello-identity-verification
For the fingerprinters, you should also check the requirements of the fingerprint readers over here:
https://learn.microsoft.com/en-us/windows-hardware/design/device-experiences/windows-hello-biometric-requirements
Best regards,
Leon