Microsoft 365 features that help users manage their subscriptions, account settings, and billing information.
Hello Mike,
I am glad to help you here. After looking through your whole post for several times, it main problem you got is you know the full admin email account, but don't know the password to login Microsoft 365 admin portal to un-tie the company domain from that tenant, please clarify if I misunderstand your scenario, thanks.
If so, first it is recommended contact another global admin of the "admin account" tenant to help reset the password, however my undertstanding is it maybe the only admin or you don't know the other admins in this round. For this case I'd like to share with you as the admin password is related to Microsoft customers' high level privacy, currently we don't have enough rights/resource on the admin account issue in the forum. And it could be only supported by the Microsoft 365 backend data protection team. So to get further assistance and help you quickly, it is recommended please directly contact Microsoft 365 Business Global Support based on your country or region and contact the back team to report your issue there, thanks.
Your understanding and patience will be highly appreciated.
Best Regards,
Oliver