Hi Daryl Williams •,
Welcome to Microsoft Q&A forum.
As I understand, you want to migrate a PostgreSQL database from Single Server to Flex Server, change the users to Entra authenticated, and then migrate the database again without users.
Microsoft Entra ID users present on your source server aren't migrated to the target server. To mitigate this limitation, visit Manage Microsoft Entra roles to manually create all Microsoft Entra users on your target server before triggering a migration. If Microsoft Entra users aren't created on target server, migration fail.
The migration service only supports users and roles migration when the source is Azure Database for PostgreSQL single server.
Please refer to https://learn.microsoft.com/en-us/azure/postgresql/migrate/migration-service/concepts-known-issues-migration-service for more details.
Thanks.