Hi Phil. It probably won't make sense until you give it a try. If you don't alias the columns, the result of the UNION query will just use the field names of the first table you listed in the SQL statement. So, if you want the result to use a different column name, you can alias those fields. Here's an example:
SELECT Field1 AS F1, Field2 AS F2, Field3 AS F3 FROM Table1
UNION ALL
SELECT FieldA, FieldB, FieldC FROM Table2
UNION ALL
SELECT FirstName, MiddleName, LastName FROM Table3
ORDER BY F1, F2 F3
Hope that helps...