Using Classic Outlook on Windows for personal email, calendar, and contact management
Hi,
Thank you for posting, I am here to help. To block sender please follow this steps:
To block messages from specific email addresses or domains from reaching your inbox. When you add an email address or domain to your blocked senders list, Outlook automatically moves messages from that sender to the Junk Email folder.
When you block an account in Outlook, it will not appear in Teams people picking and search unless you have interacted with that account in Teams. You can still call/chat with this person by typing their complete email address (Teams tenant policies will apply).
Open Outlook then go to Settings and select Mail. Open Junk email enter the email address in Blocked senders and select Add. If you want to block all email from a domain, enter the domain name in Blocked domains and select Add and select save.
For more details you can check this article:
I hope you find this information helpful. Please let us know if you have any further questions If the answer is helpful, please click "Accept Answer".
Best regards,
Jansher