Your screenshot indicates that Windows was originally installed on the top drive, and you have now installed Windows on the bottom drive, is that correct?
If so, when you install Windows, if there was a previous Windows installation on the other drive, Windows will use the boot partition on that drive and will not create a new boot partition on the bottom drive, the only way to avoid that is to re-install Windows again and before the installation, disconnect that top drive, that will force the Windows installation to create a boot partition on the bottom drive.