Hello there,
Based on the error message, we can find that the connection request did not match a configured connection request policy, so the connection request was denied by Network Policy Server.
To troubleshoot this issue, please perform the following steps.
- On the server running NPS, click Start, click Run, type nps.msc, and press ENTER.
- In the NPS console tree, open Policies\Connection Request Policies. Review the configuration and processing order of the connection request policy used to match NAP client access requests.
- In the NPS console tree, open Policies\Network Policies. Review the configuration and processing order of the network policy used to match NAP client access requests.
- If no errors are found in the connection request policy or network policy configuration, check the status of the NAP Agent on the client's computer and confirm the enforcement client is enabled.
Advanced troubleshooting 802.1X authentication https://learn.microsoft.com/en-us/troubleshoot/windows-client/networking/802-1x-authentication-issues-troubleshooting
Similar discussion here https://techcommunity.microsoft.com/t5/windows-server-for-it-pro/windows-11-clients-cannot-authenticate-to-nps-server-using/m-p/2827382
Hope this resolves your Query !!
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