There is no option for adding windows admin username & password while creating the new nodepool . Those credentials needs to be added at the time of AKS cluster creation.
From the below document , the command az aks nodepool add - you don't see any flag for --windows-admin-username & --windows-admin-password.
https://learn.microsoft.com/en-us/cli/azure/aks/nodepool?view=azure-cli-latest#az-aks-nodepool-add
Those are available only at the time of AKS cluster creation (see the command az aks create in below official document)
https://learn.microsoft.com/en-us/cli/azure/aks?view=azure-cli-latest#az-aks-create
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While creating the AKS cluster , if you have not added the windows-admin-username - there will be a default user name called : azureuser (You can get those details from az aks show -g resourcegroupname -n aksclustername)
You can use the new password by going to Azure Portal windows VMSS nodes -> Reset Password.
Hope that explanation helps ! Kindly Let us know if you have any additional questions !!
Regards,
Shiva.