Get-Content reads the content of files, like a text file. You are trying to read a directory. That won't work. You need to use this command to list the file names.
Get-ChildItem C:\Windows\system32\WindowsPowerShell\v1.0\Modules -recurse
and this user's flag is hidden in one of them.
What does that mean? Are you looking for a file with a certain name? Or are you looking for some specific text string in a file?
That folder is only for installed Powershell modules. There should be no user specific data in that folder structure.