Hi,
This issue could be caused by a variety of factors. One potential cause could be that the alert notifications are not meeting the defined criteria for the recipients' subscriptions or that notification is configured incorrectly. Another potential cause could be that the SMTP server's address or port is blocked by firewall rules or anti-malware software, which can prevent the notifications from being sent.
Since you have checked the SMTP server connection and logs, it is possible that the issue is related to the recipients' subscriptions or notification configuration. You may want to review the notification settings to ensure that they are configured correctly and that the recipients have subscriptions that match the criteria for the alerts.
If the issue persists, you may want to review the firewall rules and anti-malware software settings to ensure that they are not blocking the notification traffic. You can also try creating exclusions for the resource pool servers in the firewall rules and anti-malware software settings, as mentioned in the Microsoft documentation.
Lastly, you may want to review the event logs on the management servers to see if there are any error messages or warnings related to the failed alert notifications. This may provide additional information about the cause of the issue.