Thank you for posting your query on Microsoft Q&A, from above description I could understand that the value _ResolvedTime in format R:time is not getting converted by todatetime function which ends up in an empty value.
Please do correct me if this is not the ask by responding in the comments section.
This issue is more related to KQL rather then Sentinel but the best shot I gave was the format.
todatetime() function and datetime() literals follows ISO 8601 and it is strongly recommended to use only the ISO 8601 formats.
My suggestion here is to use format_datetime() instead of directly using R:time with todatetime() function.
Thanks,
Akshay Kaushik
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