@DheemanDas-0192
It seems like you may need to remove the existing ImmutableID from the account, so it's no longer considered "synced" and then possibly look into hard-matching the object to the other on-prem identity. Proceed with caution when performing such identity transformations. See the following references for more information:
Set Immutable ID to $Null, Soft-Match/Hard-Match in O365
Explained: User Hard Matching and Soft Matching in Azure AD Connect
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